ASGAMAGE

    A research project to find out more about the way the sea and the atmosphere exchange greenhouse gases


    Here's a quick guide to our web site:
     
    • If you want to know why ASGAMAGE might be important for your future, but you are not familiar with climate research, look at: ASGAMAGE.... what's that,
    • If you're a bit more knowledgeable in climate research, try state of the project
    • If you want to know which institutes participated, we have an item project organization
    • If you're in too much of a hurry to read those pages and reasonably well acquainted with air-sea gas exchange work, here's a short summary. Several links to figures and texts will give you some more background information in case you decide that you have somewhat more time after all.

    Summary

    Objectives
    Field experiments
    Main Conclusions
    Acknowledgements
    References

    Objectives

    1. To find relationships between the transport coefficients for the gas fluxes and any relevant geophysical parameters.
    2. To test new methods and new equipment for the measurement of air-sea fluxes of CO2, DMS and other gases.
    3. To intercompare different methods and systems to measure the transfer velocity of trace gases over the sea.
    4. To find out whether and, if at all, under what conditions there can be a significant vertical gradients in the carbon dioxide concentration in the upper meters of the water column.

    5.  
    [More about the objectives]
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    Field experiments

    Experiments for ASGAMAGE, the MAGE project of the Air Sea GAs exchange programme, took place in May and October of 1996. The experiments were performed at and around Meetpost Noordwijk (MPN), a research platform situated 9 km off the Dutch coast, and from the UK research vessel "RRS Challenger", operating in the neighbourhood of the platform. At MPN numerous meteorological and oceanographic observations were performed. The activities on the "Challenger" were primarily devoted to the differential tracer experiment (tracer preparation, tracer release, sampling, analysis) and to meteorological observations.

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    Conclusions

    • The eddy correlation (ec) and differential tracer (dt) results for the transfer velocity velocity of CO2 are within a factor of two to three from each other. The scatter in the data is considerable. Some possible causes for the remaining difference and the large scatter could be identified:
      • The ec data indicate a diurnal trend in the transfer velocity, in the order of a factor of two, which may be related to the sea water temperature. Because the majority of the ec runs was made during the daytime, when the fluxes were higher than at night, the resulting average was about 8% too high.
      • Computer model simulations of dt experiments suggest the existence of near-surface (depth less than 1 m) concentration gradients of inert tracers, which may cause a negative bias in dt results (10-30%).
      • Similar simulations of ec measurements of CO2 fluxes indicate that some 50% or more of the scatter in the data may be caused by the presence of small patches of water with enhanced biological activity.
    • The uncertainty in the data is still too high to detect dependencies that are more subtle than the one with the wind.
      • Of the two main contenders for the relationship between the transfer velocity and the wind, the Liss-Merlivat (1986) and the Wanninkhof (1992) parameterizations, the one due to Wanninkhof agrees best with the experimental results.
    • Differences between the results from the various independent ec measurements can largely be attributed to differences in the sensitivity of the instruments to fluctuations in the water vapour concentration in the atmosphere.
    • The relaxed eddy accumulation measurements on DMS have provided sensible results, those on CO2 were unsuccessful.
    • CO2 concentration gradients in the upper meters of the sea, seen during the '96 experiment were very much smaller than those of the '93 experiment.
    • (Technical) The use of (semi) open-path CO2 detectors, based on the absorption of infrared radiation, requires absolute cleanliness of the optical elements exposed to the air stream.


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    Acknowledgements

    The European institutes participating in ASGAMAGE were supported by the MAST-3 programme of the European Union under contract MAS3-CT95-0044. The UK Natural Environment Research Council provided ship time for the DT measurements as part of its ACSOE thematic program. ASGAMAGE was an integral component of the international Marine Aerosol and Gas Exchange (MAGE) initiative, a sub-activity of the International Global Atmospheric Chemistry (IGAC) core project of the International Geosphere-Biosphere Program (IGBP)

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    References

    Liss, P.S. and L. Merlivat, 1986: Air-sea gas exchange rates: introduction and synthesis. In: P. Buat Ménard (Ed.), The role of air-sea exchange in geochemical cycling, D.Reidel Publishing Company, Dordrecht, 113-128.

    Wanninkhof, R., 1992: Relationship between wind speed and gas exchange over the ocean. J. Geophys. Res., 97, 7373-7382.

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